Analysis of Complex Species Produced by the Szillard-Chalmers Process from Hexaquo-chromium Chloride Cr(H2O)6Cl3and Tetraquo-chromium Chloride [Cr(H2O)4Cl2]·Cl·2H2O
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منابع مشابه
cis-Dichloridobis(1,10-phenanthroline)chromium(III) chloride
In the title complex, [CrCl(2)(C(12)H(8)N(2))(2)]Cl, the Cr(III) ion is situated on a twofold rotation axis and displays a slightly distorted octa-hedral CrCl(2)N(4) coordination geometry. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline and two chloride ligands. The chloride counter-anion exhibits half-occupation and is equally disordered over two positions.
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A n h y d r o u s c h r o m i u m ( I I I ) c h l o r i d e r e a c t s w i t h p u r e c a r b o x y l i c a c i d s ( R C O O H w h e r e R = C H 3 , C 2 H 5 , n C 3 H 7 , C H 2 C I , C H C I 2 a n d C C 1 3 ) t o g i v e b a s i c t r i n u c l e a r c h r o m i u m ( I I I ) c a r b o x y l a t e s o f t h e g e n e r a l f o r m u l a [ C r 3 0 ( 0 0 C R ) 6 ] + C l ~ . T h e r e a c t i o...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1962
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.35.1697